(4+2)-cycloadditions of substituted arenediazocyanides: A kinetic study of a new dienophile |
| |
| Authors: | Duane P. Gapinski Michael F. Ahern |
| |
| Affiliation: | Department of Chemistry, United States Military Academy West Point, New York 10996 U.S.A. |
| |
| Abstract: | The rate constants of the (4+2)-cycloaddition reaction between substituted -arenediazocyanides and 2,3-dimethyl-1,3-butadiene have been determined in several solvents. The reaction displays linear Hammett behavior; the data suggest a concerted reaction mechanism. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
