Preparation and synthetic application of 2-bromoallyltrimethylsilane as a 1-hydroxymethylvinyl anion equivalent |
| |
| Authors: | Hisao Nishiyama Hiroshi Yokoyama Shinzo Narimatsu Kenji Itoh |
| |
| Affiliation: | School of Materials Science, Toyohashi University of Technology, Tempaku-cho, Toyohashi, 440 Japan |
| |
| Abstract: | ![]()
The 1-trimethylsilylmethylvinyl group, as a 1-hydroxymethylvinyl equivalent, was readily introduced to epoxides with the corresponding Grignard reagent derived from 2-bromoallyltrimethylsilane. Obtained 2-(2-hydroxy-ethyl)-allylsilanes were converted to α-methylene-γ-lactones via diols. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
