One-step synthesis of 4-aminodihydrobenzofurans and 4-hydroxyindoles via dehydrogenation-heteromercuration of 2-alyl-3-aminocyclohexenones using mercury(II) acetate |
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| Authors: | Hideo Iida Yoshifumi Yuasa Chichiro Kibayashi |
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| Institution: | Tokyo College of Pharmacy, Horinouci, Hachioji, Tokyo 192-03, Japan |
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| Abstract: | On treatment of the 2-allyl-3-aminocyclohexenones with mercury(II) acetate, either sequence, dehydrogenation—oxymercuration or dehydrogenation—aminomercuration, occurred depending on the nature of the amino group in the substrate to yield the dihydrobenzofurans or indoles, respectively. |
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