Magnetic study of highly conductive TCNQ salts of Cu(II) complexes with 2,2'-bipyridine, 1,10-phenanthroline and ethylenediamine |
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| Authors: | Michiko B Inoue Motomichi Inoue |
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| Institution: | Departamento de Quimica, ICET, Universidad Autónoma de Guadalajara, Guadalajara, Mexico |
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| Abstract: | The magnetic susceptibility has been determined for CuLn(TCNQ−)2 (L = 2,2'-bipyridine, 1,10-phenanthroline, or ethylenediamine;n = 1 or 2), having high electric conductivity. The results show that the Cu2+Ln chelates are partially reduced to Cu2+Ln in the complexes. The equilibrium Cu2+Ln(TCNQ−)2  Cu+Ln(TCNQ−)(TCNQo) produces conduction electrons in TCNQ columns. |
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