Palladium(II) benzazolylformazanates: Synthesis,structure and optical properties |
| |
| Authors: | G. N. Lipunova Z. G. Rezinskikh T. I. Maslakova P. A. Slepukhin I. G. Pervova I. N. Lipunov G. I. Sigeikin |
| |
| Affiliation: | (1) Ural State Technical University, Yekaterinburg, Russia;(2) Ural State Forestry University, Yekaterinburg, Russia;(3) Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russia;(4) Interdepartmental Center for Analytical Research at the Presidium of the Russian Academy of Sciences, Moscow, Russia |
| |
| Abstract: | The Pd(II) complexes of 1-aryl-5-benzazolyl- and 1,5-dibenzimidazolylformazans are synthesized and characterized by UV and IR spectroscopy, mass spectrometry, and magnetochemical studies. The complexes exhibit the intense absorption in the near-IR spectral region (820–1020 nm). The interaction of the complexes with amines leads to the transformation into binuclear palladium formazanates, which absorb at 620–680 nm and whose structures were confirmed by X-ray diffraction analysis. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
