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Ionic-conductivity switching of vinyl malachite green leuconitrile copolymers based on photoinduced carrier generation
Authors:Keiichi Kimura  Masayuki Kaneshige  Hideo Tokuhisa  Masaaki Yokoyama
Abstract:Copolymers of bis4-(N,N-dimethylamino)phenyl]-4-vinylphenylmethanenitrile (vinyl Malachite Green leuconitrile) with methyl methacrylate or ω-methoxyoligo(oxyethylene) methacrylate have been synthesized, aiming at designing one-component-type organic polymers for photoswitchable ion-conducting films. The triphenylmethanenitrile copolymers with ω-methoxyoligo(oxyethylene) methacrylate were found to undergo ionic-conductivity switching by turning on and off UV light at ambient temperature, owing to their low glass transition temperature. © 1993 John Wiley & Sons, Inc.
Keywords:Malachite Green vinyl polymer  ionic conductivity  photoinduced switching  single-ionic  carrier generation
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