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Determination of higher molecular weight aliphatic aldehydes and ketones
Authors:Aubrey P Altshuller  Israel R Cohen
Institution:Air Pollution Engineering Research, Robert A. Taft Sanitary Engineering Center, Public Health Service, U. S. Department of Health, Education and Welfare, Cincinnati, OhioU.S.A.
Abstract:The visible absorption spectra have been measured for the reaction products formed by aldehydes and ketones with p-nitrobenzenediazonium fluoborate in a phosphoric acid-2-methoxyethanol solvent medium. The absorption maxima for the reaction products of higher molecular weight aldehydes and ketones are much more intense than those formed by formaldehyde, acetaldehyde and acetone. This intensity effect has been used to analyze for propionaldehyde in mixtures also containing formaldehyde, acetaldehyde or acetone. The nature of the reaction products are considered.
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