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35Cl quadrupole resonance study of the thermally activated motion of the nitro group in chlorinated nitrobenzenes
Authors:I. A. Kyuntsel
Affiliation:1602. Perm State University, Perm, Russia
Abstract:The results of NQR studies of the thermoactivated motion of NO2 groups in chlorine-containing nitrobenzenes are presented. A procedure for analyzing the experimental data is suggested. It uses the characteristic temperature of the minimum of the modulation contribution to the temperature dependence of the spin-lattice relaxation time T 1 of the resonant probe nuclei (35Cl) bonded with the moving group by nonvalent interactions. The activation energy of the thermoactivated motion was correlated with the temperature of the minimum. The possibility of a temperature dependence of the activation energy of the NO2 group was examined.
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