The fractional ionic character of alkali and silver halide crystals |
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Authors: | Jai Shanker M P Verma |
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Institution: | (1) Department of Physics, Agra College, 282002 Agra |
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Abstract: | The fractional ionic character of alkali and silver halide crystals is defined in terms of the deviations from the additivity
rule for polarizabilities of ions. The electronic polarizabilities of ions are calculated using an empirical relationship
according to which the electronic polarizability of an ion can be assumed to be directly proportional to the cube of its radius.
The calculated ionicities indicate that the alkali halides are nearly or more than 90% ionic and silver halides are much less
ionic which is also evident from the Phillips ionicity scale. |
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Keywords: | Fractional ionic character alkali halide crystals silver halide crystals Phillips ionicity |
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