超临界二氧化碳介质中的有机反应*

本文主要介绍了超临界近5年来超临界二氧化碳中的有机反应研究的最新进展，包括加氢反应、氧化反应、羰基化反应、碳碳键形成反应、酯化反应和酶催化反应的研究现状；同时，还介绍了超临界二氧化碳作为反应底物用于合成碳酸酯和氨基甲酸酯的研究进展；并对未来的发展进行了展望。

Organic Reactions in Supercritical Carbon Dioxide

The progress on organic reactions in supercritical carbon dioxide in recent five year is reviewed in this paper, which includes hydrogenation, oxidation, carbonylation, carbon-carbon bond formation, esterification and enzymatic reaction. The synthesis of carbonates and carbamates using supercritical carbon dioxide as substrate is also discussed. The outlook of the research area is provided. Contents 
1 Introduction 
2 Hydrogenation 
2.1 Asymetric hydrogenation 
2.2 Hydrogenation of phenols 
2.3 Hydrogenation of nitroaromatics 
2.4 Other hydrogenations 
3 Oxidation 
3.1 Oxidation of alcohols 
3.2 Oxidation of hydrocarbons 
3.3 Wacker reaction
3.4 Baeyer-Villiger reaction 
4 Carbonylation 
4.1 Hydroformylation
4.2 Hydrocarboxylation 
4.3 Hydroesterification 
5 Carbon-Carbon bond formation 
5.1 Friedel-Crafts alkylation 
5.2 Aldol reaction 
5.3 Coupling reaction 
5.4 Cyclotrimerization 
5.5 Hydrovinylation
6 Esterification 
7 Enzymatic reaction 
8 Supercritical carbon dioxide as substrate 
8.1 Synthesis of carbonates
8.2 Synthesis of carbamates 
9 Conclusions and outlook