Kinetics and mechanism of ketone-bisulfite addition reaction in aqueous solution |
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| Authors: | T. S. Rao and S. B. Salunke |
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| Affiliation: | (1) Department of Chemistry, University of Poona, 411 007 Pune, India |
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| Abstract: | The kinetics of the addition of bisulfite to acetone has been studied by the polarographic technique. The specific rate increases with pH and hence the reaction is probably base catalyzed. Mechanisms have been suggested for the reaction in the presence and absence of added base.
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