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Internal pressure of solid poly(ethylene oxide) 6000 swollen with liquid poly(ethylene oxide) 200
Authors:K.S. Chan  C. Booth  C. Price
Affiliation:Department of Chemistry, University of Manchester, Manchester, M13 9PL, U.K.
Abstract:Internal pressures (Pi) have been measured at low external pressure for solid poly(ethylene oxide) 6000 and solid poly(ethylene oxide) 6000 swollen with 5% by weight liquid poly(ethylene oxide) 200. Values of Pi are low (Pi < 108 Pa at 10°). The effect of swelling with liquid, which is located exclusively within the disordered layers of the solid, is that expected on the basis of additivity.
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