| 二茂铁在汽油抗爆剂组分中电子转移性能及H2O2的影响 |
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| 引用本文： | 郁章玉,秦梅,齐丽云,汪汉卿,王慧云.二茂铁在汽油抗爆剂组分中电子转移性能及H2O2的影响[J].应用化学,2004,21(12):1229-0. |
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| 作者姓名： | 郁章玉 秦梅 齐丽云 汪汉卿 王慧云 |
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| 作者单位： | 中国科学院，石油大学，曲阜师范大学 |
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| 基金项目： | 国家自然科学基金 ( 2 9673 0 2 5 )，山东省自然科学基金 (Y2 0 0 0B0 3 )资助项目 |
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| 摘 要： | 二茂铁在汽油抗爆剂组分中电子转移性能及H2O2的影响;二茂铁;过氧化氢;电子转移机理;抗爆剂
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| 关 键 词： | 二茂铁在汽油抗爆剂组分中电子转移性能及H2O2的影响 二茂铁 过氧化氢 电子转移机理 抗爆剂 |
| 文章编号： | 1000-0518(2004)12-1229-04 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2004年2月27日 |
Electron-Transfer Properties of Ferrocene and Influence of Hydrogen Peroxide on Them in Antiknock Additive for Gasoline |
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| YU Zhang-Yu a,c,QIN Mei b,QI Li-Yun b,WANG Han-Qing a,WANG Hui-Yun b.Electron-Transfer Properties of Ferrocene and Influence of Hydrogen Peroxide on Them in Antiknock Additive for Gasoline[J].Chinese Journal of Applied Chemistry,2004,21(12):1229-0. |
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| Authors: | YU Zhang-Yu a c QIN Mei b QI Li-Yun b WANG Han-Qing a WANG Hui-Yun b |
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| Institution: | YU Zhang-Yu a,c*,QIN Mei b,QI Li-Yun b,WANG Han-Qing a,WANG Hui-Yun b |
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| Abstract: | The auxiliaries of gasoline antiknock additive TKC were analysed by means of gas chromatography/mass spectrometry. The main auxiliary components were found to be toluene, dichloroethane, tetrachloroethy- lene, and butyl acetate. The electrochemical properties of ferrocene in the auxiliary additive in the presence and the absence of hydrogen peroxide were investigated at a platinum electrode by cyclic voltammetry. The electrode processes and cooperative effect of the additive components were determined. All the electrode reactions in the various media followed the catalytic EC(electron transfer-chemical reaction) mechanism. |
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| Keywords: | ferrocene hydrogen peroxide electron transfer mechanism antiknock additive |
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