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TE011腔使用扁平样品管提高水溶液样品ESR波谱灵敏度的研究
引用本文:陈炳焕,蔡同茂,万谦. TE011腔使用扁平样品管提高水溶液样品ESR波谱灵敏度的研究[J]. 波谱学杂志, 1987, 4(3): 259-264
作者姓名:陈炳焕  蔡同茂  万谦
作者单位:中国科学院生物物理研究所
摘    要:
实验表明,在TE011模式园柱形腔中,不但可以使用扁平样品管测量水溶液样品的ESR波谱,而且获得好的腔品质因子Q和高品质的ESR信号。所观察到的信号高度,是使用最佳尺寸毛细管样品时最大信号高度的3.2倍;又是在具有波导尺寸的TE102腔中使用扁平样品管时所获得信号高度的3倍。本文对此作了定性的理论分析。

关 键 词:电子自旋共振(ESR)  电子自旋共振波谱仪灵敏度  TE011模式园柱形谐振腔  扁平样品管  
收稿时间:1986-12-01

THE STUDIES OF INCREASING THE SENSITIVITY OF ESR SPECTRUM OF AQUEOUS SAMPLE IN TE_(011) MODE CAVITY WITH FLAT CELLS
Chen Binghuan Cai Tongmao and Wan Qian. THE STUDIES OF INCREASING THE SENSITIVITY OF ESR SPECTRUM OF AQUEOUS SAMPLE IN TE_(011) MODE CAVITY WITH FLAT CELLS[J]. Chinese Journal of Magnetic Resonance, 1987, 4(3): 259-264
Authors:Chen Binghuan Cai Tongmao and Wan Qian
Affiliation:Institute of Biophysics, Academia Sinica
Abstract:
The experimental results show that flat sample cell not only can be used to measure ESR spectrum of aqueous sample in a TE011 mode cylindrical cavity,but also gives a good cavity quality factor Q and high quality ESR signals. The observed signal height was 3.2 times as large as the maximum signal height that can be obtained when a capillary tube with optimum size was used in the same cavity, and 3 times as large as the signal height when a flat cell was used in a TE102 mode rectangular cavity with waveguide size. In this paper,a theoretical analysis is given.
Keywords:electron spin resonance(ESR)  sensitivity of ESR spectrometer  TE_(011) mode cylindrical cavity  flat sample cell.
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