ESR spectroscopic study on the addition of PhCONHCHCO2Me radicals to alkenes and spin traps |
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Authors: | R G Gasanov |
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Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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Abstract: | Using ESR spectroscopy, the rate constants for the addition of PhCONHCHCO2Me radicals to alkenes CH2=CXY (X = Me, Y = Ph; X = H, Y = Ph; X = Me, Y = CO2Me; X = H, Y = CO2Me; X = H, Y = CN) and nitrosodurene were determined at 22 °C. It is shown that a linear dependence exists between the donor-acceptor properties of the substituents at the vinyl group and the rate constants for the addition.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2124–2126, August, 1996. |
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Keywords: | spin trap method rate constants for addition alkenes |
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