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Regio- and stereoselective synthesis of novel (E)-1-alkenyl carbamate via carbocupration reaction
Authors:Chechik-Lankin Helena  Marek Ilan
Affiliation:Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Technion City, Haifa 32000, Israel. chilanm@tx.technion.ac.il
Abstract:The stereoselective carbocupration and copper-catalyzed carbomagnesiation reactions of alkynyl carbamates are described as a new and straightforward method for the preparation of (E)-alkenyl enol carbamates. [reaction: see text]
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