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Correlations between Van der Waals' volume and retention index general equation applicable to different homologous series
Authors:F Saura Calixto  A García Raso
Institution:(1) Department of Organic Chemistry, Science Faculty, The University of Palma de Mallorca, Spain
Abstract:Summary Correlations between retention index (RI) and Van der Waals' volume (VW) in homologous series of n-alcohols, n-aldehydes and esters are studied on the stationary phases Carbowax 1540 and squalane. Influence of functional groups is quantified and a method for obtaining one general equation, valid for an indeterminate number of homologous series, is proposed.
Keywords:Capillary gas chromatography  Retention index  Van der Waals' volume
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