Correlations between Van der Waals' volume and retention index general equation applicable to different homologous series |
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Authors: | F Saura Calixto A García Raso |
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Institution: | (1) Department of Organic Chemistry, Science Faculty, The University of Palma de Mallorca, Spain |
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Abstract: | Summary Correlations between retention index (RI) and Van der Waals' volume (VW) in homologous series of n-alcohols, n-aldehydes and esters are studied on the stationary phases Carbowax 1540 and squalane. Influence of functional groups is quantified and a method for obtaining one general equation, valid for an indeterminate number of homologous series, is proposed. |
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Keywords: | Capillary gas chromatography Retention index Van der Waals' volume |
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