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| One Pot Reduction of Imines Generated in-situ from Aldehydes and Amines by the NaBH4-InCl3 System | |
| 引用本文： | RAVI Varala,RAMU Enugala,VIJAY KUMAR Ponnamaneni,SRINIVAS RAO Adapa. One Pot Reduction of Imines Generated in-situ from Aldehydes and Amines by the NaBH4-InCl3 System[J]. 中国化学, 2006, 24(6): 807-810. DOI: 10.1002/cjoc.200690153 |
| 作者姓名： | RAVI Varala RAMU Enugala VIJAY KUMAR Ponnamaneni SRINIVAS RAO Adapa |
| 作者单位： | Indian Institute of Chemical Technology, Hyderabad-500 007, India |
| 基金项目： | Acknowledgement RAVI, Varala thanks Council of Scientific and Industrial Research （CSIR）, India for the award of senior research fellowship （SRF）. |
| 摘 要： | A combination of sodium borohydride and a catalytic amount of indium（Ⅲ） chloride in acetonitrile reduces imines formed in-situ from aldehydes and amines to the corresponding functionalised secondary and tertiary amines in moderate to good yields. Noteworthy is that highly chemoselective reactions were achieved in the presence of other functional groups such as halogens, carbon-carbon double bonds and hydroxyl groups. |
| 关 键 词： | NaBH4-InCl3系统 乙醛 胺 一罐合成 亚胺 氯化铟 |
| 收稿时间： | 2005-08-22 |
| 修稿时间： | 2005-08-222006-02-10 |
One Pot Reduction of Imines Generated in-situ from Aldehydes and Amines by the NaBH4-InCl3 System |
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| RAVI,;Varala;RAMU,;Enugala;VIJAY;KUMAR,;Ponnamaneni;SRINIVAS;RAO,;Adapa. One Pot Reduction of Imines Generated in-situ from Aldehydes and Amines by the NaBH4-InCl3 System[J]. Chinese Journal of Chemistry, 2006, 24(6): 807-810. DOI: 10.1002/cjoc.200690153 | |
| Authors: | RAVI, Varala RAMU, Enugala VIJAY KUMAR, Ponnamaneni SRINIVAS RAO, Adapa |
| Abstract: | A combination of sodium borohydride and a catalytic amount of indium(III) chloride in acetonitrile reduces imines formed in‐situ from aldehydes and amines to the corresponding functionalised secondary and tertiary amines in moderate to good yields. Noteworthy is that highly chemoselective reactions were achieved in the presence of other functional groups such as halogens, carbon‐carbon double bonds and hydroxyl groups. |
| Keywords: | NaBH4-InCl3 aldehyde amine One Pot Reduction |
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