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Asymmetric synthesis of polymer-supported cyanohydrin acetates |
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| Authors: | Yuri N Belokon’ Michael North |
| Institution: | a A.N. Nesmeyanov Institute of Organo-Element Compounds, Russian Academy of Sciences, 119991, Moscow, Vavilov 28, Russian Federation b Department of Chemistry, King’s College London, Strand, London WC2R 2LS, UK c School of Natural Sciences, Bedson Building, University of Newcastle, Newcastle upon Tyne NE1 7RU, UK |
| Abstract: | A bimetallic titanium(salen) complex has been used to catalyze the asymmetric addition of potassium cyanide to aldehydes attached to Wang resin giving polymer supported cyanohydrin propionates with up to 91% enantiomeric excesses. |
| Keywords: | Cyanohydrin Catalysis Asymmetric Polymer |
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