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A highly efficient synthesis of unnatural l-sugars from d-ribose |
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| Authors: | Mikyung Yun Hea Ok Kim Yong-Chul Kim Lak Shin Jeong |
| Affiliation: | a Laboratory of Medicinal Chemistry, College of Pharmacy, Ewha Womans University, Seoul 120-750, Korea b College of Pharmacy, Pusan National University, Pusan 609-735, Korea c Department of Life Science, Gwangju Institute of Science and Technology, Gwangju 500-712, Korea |
| Abstract: | A preparative and short synthesis of l-ribose and l-apiose was accomplished starting from d-ribose via stereoselective cis-dihydroxylation and C2-hydroxymethylation, respectively. These l-sugars can serve as versatile intermediates for the synthesis of l-nucleosides. |
| Keywords: | smallcaps" >l-Ribose smallcaps" >l-Apiose cis-Dihydroxylation Hydroxymethylation |
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