Ring-opening reactions of arylvinylidenecyclopropanes with diaryl diselenide upon heating: formation of 1,2-diarylselenocyclopentene derivatives |
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| Authors: | Min Shi Jian-Mei Lu |
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| Affiliation: | a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China
b School of Chemistry and Pharmaceutics, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China |
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| Abstract: | Arylvinylidenecyclopropanes undergo a novel reaction upon heating at 150 °C with diaryl diselenide to give the corresponding 1,2-diarylselenocyclopentene derivatives in good to high yields within 1.5 h. The further transformation of 1,2-diarylselenocyclopentene derivatives has been disclosed. |
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| Keywords: | Arylvinylidenecyclopropanes Diaryl diselenides Cyclopentene derivatives Heating |
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