A novel glycosylation concept; microwave-assisted acetal-exchange type glycosylations from methyl glycosides as donors |
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| Authors: | Yayoi Yoshimura Hiroshi Hinou |
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| Institution: | a Division of Biological Sciences, Graduate School of Science, Frontier Research Center for the Post-Genome Science and Technology, Hokkaido University, N21 W11, Sapporo 001-0021, Japan
b Glycochemosynthesis Team, Research Center for Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST), Sapporo 062-8517, Japan |
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| Abstract: | Efficient microwave-assisted glycosylations from methyl glucopyranosides are described. We have discussed the effects of microwave irradiation on this unique glycoside exchanging reaction from view points such as amount of Lewis acid promoters and acceptors, hydroxyl protecting groups of methyl glucopyranosides donors for reactivity, and neighboring effect. |
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| Keywords: | Microwave Glycosylation Carbohydrate Methyl glycoside |
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