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1H and 13C NMR assignments of eight nitrogen containing compounds from Nocardia alba sp.nov (YIM 30243T)
Authors:Zhang‐Gui Ding  Jiang‐Yuan Zhao  Pei‐Wen Yang  Ming‐Gang Li  Rong Huang  Xiao‐Long Cui  Meng‐Liang Wen
Institution:1. Key Laboratory for Microbial Resources, Ministry of Education, Yunnan Institute of Microbiology, Yunnan University, Kunming, Yunnan 650091, P. R. China;2. Institute of Agriculture Environment and Resource, Yunnan Academy of Agricultural Sciences, Kunming, Yunnan 650205, P. R. China;3. Key Laboratory of Medicinal Chemistry for Natural Resources, Ministry of Education, Yunnan University, Kunming, Yunnan 650091, P. R. China
Abstract:An unprecedented new natural product named nocarsin A (1), 5H‐4a,6,7a‐triazacyclopentacd]indene‐5,7(6H)‐dione (1), together with seven known compounds lumichrome (2), cyclo (L ‐Leu‐L ‐Tyr) (3), cyclo (L ‐Ala‐L ‐Ile) (4), cyclo (L ‐Ala‐L ‐Leu) (5), cyclo (L ‐Val‐L ‐Ala) (6), 5‐methyluracil (7) and uracil (8), was isolated from Nocardia alba sp.nov (YIM 30243T), which was isolated from a soil sample collected from Yunnan Province, P. R. China. NMR techniques including COSY, HSQC, ROESY, and HMBC were used to elucidate the structures of these compounds. We report the unambiguous assignments of the 1H and 13C NMR spectra of the new compound nocarsin A (1). Copyright © 2009 John Wiley & Sons, Ltd.
Keywords:1H NMR  13C NMR  2D NMR  nocarsin A  lumichrome  cyclopeptides  Nocardia alba sp  nov
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