Controlled/living heterogeneous radical polymerization in supercritical carbon dioxide |
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| Authors: | Per B Zetterlund Fawaz Aldabbagh Masayoshi Okubo |
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| Institution: | 1. Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Kobe 657‐8501, Japan;2. School of Chemistry, National University of Ireland, Galway, Ireland |
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| Abstract: | Supercritical carbon dioxide (scCO2) is an inexpensive and environmentally friendly medium for radical polymerizations. ScCO2 is suited for heterogeneous controlled/living radical polymerizations (CLRPs), since the monomer, initiator, and control reagents (nitroxide, etc.) are soluble, but the polymer formed is insoluble beyond a critical degree of polymerization (Jcrit). The precipitated polymer can continue growing in (only) the particle phase giving living polymer of controlled well‐defined microstructure. The addition of a colloidal stabilizer gives a dispersion polymerization with well‐defined colloidal particles being formed. In recent years, nitroxide‐mediated polymerization (NMP), atom transfer radical polymerization (ATRP), and reversible addition fragmentation chain transfer (RAFT) polymerization have all been conducted as heterogeneous polymerizations in scCO2. This Highlight reviews this recent body of work, and describes the unique characteristics of scCO2 that allows composite particle formation of unique morphology to be achieved. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 3711–3728, 2009 |
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| Keywords: | dispersions living radical polymerization (LRP) particle radical polymerization supercritical fluids |
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