Poly(cyclohexene oxide)/clay nanocomposites by photoinitiated cationic polymerization via activated monomer mechanism |
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| Authors: | Ayhan Oral Mehmet Atilla Tasdelen Adem Levent Demirel Yusuf Yagci |
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| Institution: | 1. Department of Chemistry, Faculty of Sciences and Arts, Canakkale Onsekiz Mart University, 17020, Canakkale, Turkey;2. Department of Chemistry, Istanbul Technical University, 34469, Maslak, Istanbul, Turkey;3. Chemistry Department, Koc University, Rumelifeneri Yolu, 34450, Sariyer, Istanbul, Turkey |
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| Abstract: | Poly(cyclohexene oxide) (PCHO)/clay nanocomposites were prepared by in situ photoinitiated activated monomer cationic polymerization. The polymerization of cyclohexene oxide through the interlayer galleries of the clay can provide distribution of the clay layers in the polymer matrix homogenously and results in the formation of PCHO/clay nanocomposites. The exfoliated structures were characterized by X‐ray diffraction spectroscopy, thermogravimetric analysis, transmission electron microscopy, and atomic force microscopy. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5328–5335, 2009 |
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| Keywords: | activated monomer polymerization clay epoxides nanocomposites photoinitiated polymerization polyethers |
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