Enantiospecific approach to the tricyclic core structure of tricycloillicinone, ialibinones, and takaneones via ring-closing metathesis reaction |
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| Authors: | A. Srikrishna B. Beeraiah V. Gowri |
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| Affiliation: | Department of Organic Chemistry, Indian Institute of Science, C. V. Raman Avenue, Bangalore 560012, India |
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| Abstract: | Enantiospecific synthesis of the tricyclic core structure present in the biologically active natural products tricycloillicinone, ialibinones, and takaneones, starting from the readily available campholenaldehyde employing a transannular RCM reaction as the key step, has been accomplished. |
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| Keywords: | Tricyclo[5.3.1.01,5]undecane (S)-Campholenaldehyde Enantiospecific synthesis RCM reaction Diquinanes Illicinones |
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