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The elusive tetrasulfate anion [S4O13](2-) |
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| Authors: | Logemann Christian Klüner Thorsten Wickleder Mathias S |
| Affiliation: | Carl von Ossietzky University of Oldenburg, Institute for Pure and Applied Chemistry, Germany. |
| Abstract: | Sulfates united: the unique tetrasulfate S(4)O(13)(2-) anion was observed in the structure of (NO(2))(2)[S(4)O(13)] that forms in the reaction of N(2)O(5) with SO(3). Theoretical investigations show that the anion is a stable member of the polysulfate series [S(n)O(3n+1)](2-), which was investigated up to n=11. |
| Keywords: | crystal structures nitrylium ion polysulfates tetrasulfate theoretical calculations |
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