Lifetime prediction for polymers via the temperature of initial decomposition |
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Authors: | Z Dobkowski E Rudnik |
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Institution: | (1) Industrial Chemistry Research Institute, Rydygiera 8, 01-793 Warszawa, Poland |
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Abstract: | The temperature of initial decompositionT
id was determined from TG and DTG curves of mass loss during thermooxidative polymer decomposition in an environmental air atmosphere. The values ofT
id were applied for comparison of the thermal stabilities of several polymers, e.g. PC-A, PBT, PET, PPO and PVC. Both the activation energies of initial decompositionE
id and the preexponential termsA
id of the Arrhenius equation were calculated by using the Kissinger approach. The initial mass loss is proposed as a criterion for calculation of the time to failuret
f from the known values ofE
id andA
id, and hence for a prediction of the lifetime of polymer materials.The following thermal stability sequence was found for the investigated polymer materials: PC-A (st)>PC-A (nst)>PBT>PET>PPO>PVC (e)>PVC (c). The activation energy of initial decomposition had a mean value ofE
id=83 kJ mol–1 for PC-A, PBT, PET and PPO, andE
id=73 kJ mol–1 for the PVC samples.The calculated time to failure,t
f, for PC-A, PET and PVC under specified conditions was in reasonable agreement with published experimental data.The proposed parameters of thermal decompositionT
id,E
id andt
f, can be applied for the characterization and comparison of various polymer materials, and for a prediction of their lifetime.Financial support from the Polish Scientific Research Committee, the grant No. 7 761791 02, is gratefully acknowledged. |
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Keywords: | activation energy of initial decomposition comparison of thermal stability lifetime prediction temperature of initial decomposition thermal analysis of polymers |
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