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Alkoxylation of 1,2-Bis(methylchlorosilyl)ethylenes and -Acetylenes
Authors:Lakhtin  V. G.  Nosova  V. M.  Kisin  A. V.  Ivanov  P. V.  Chernyshev  E. A.
Affiliation:(1) Gosudarstvennyi nauchno-issledovatel'skii institut khimii i tekhnologii elementoorganicheskikh soedinenii State Research Center of the Russian Federation, Moscow, Russia
Abstract:
Reactions of a series of 1,2-bis(methylchlorosilyl)ethylenes and -acetylenes MenCl3-nSi-Z-SiCl3-nMen (Z = CH = CH, CequivC; n = 0-2) with ethanol and acetoxime were studied. Novel alkoxy- and isopropylideneaminooxysilanes were obtained and characterized. A relation was found between the activity of Si-Cl bonds in the reactions studied and the structure of the carbon-carbon bridge.
Keywords:
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