Alkoxylation of 1,2-Bis(methylchlorosilyl)ethylenes and -Acetylenes |
| |
Authors: | Lakhtin V. G. Nosova V. M. Kisin A. V. Ivanov P. V. Chernyshev E. A. |
| |
Affiliation: | (1) Gosudarstvennyi nauchno-issledovatel'skii institut khimii i tekhnologii elementoorganicheskikh soedinenii State Research Center of the Russian Federation, Moscow, Russia |
| |
Abstract: | Reactions of a series of 1,2-bis(methylchlorosilyl)ethylenes and -acetylenes MenCl3-nSi-Z-SiCl3-nMen (Z = CH = CH, CC; n = 0-2) with ethanol and acetoxime were studied. Novel alkoxy- and isopropylideneaminooxysilanes were obtained and characterized. A relation was found between the activity of Si-Cl bonds in the reactions studied and the structure of the carbon-carbon bridge. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |