NMR evidence for the charge transfer from interstitial NO
or O2 to molecule C60 in solid
C60 |
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Authors: | M Gu S Wang J Wu D Feng W Xu |
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Institution: | (1) National Laboratory of Solid State Microstructures, Nanjing University, Nanjing, 210093, P.R. China;(2) Institute of Chemistry and Graduate School, Chinese Academy of Science, Beijing, P.R. China |
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Abstract: | Solid C60 was stored in NO and O2 under high pressure, and the
molecule NO and O2 were found to diffuse into the octahedral
interstitial sites in its fcc crystal lattice. Their 13C NMR MAS
spectra composed of a primary resonance at 143.7 ppm, accompanied by several
minor peaks shifted downfield respectively. The spectra at various
temperatures from 210 to 300 K have been measured, and the chemical shifts
of the minor peaks referenced to the primary resonance versus inverse
temperature show straight lines. But, the lines do not go through origin,
and their intercepts are equal to 0.13 ppm or its multiple. Due to a
non-zero intercept at high-temperature limit, we proposed that there is a
charge transfer from NO and from O2 to C60. The quantity of the
charge transferred has been calculated, that is about 0.065 qe-
(qe- for the elementary charge on an electron). |
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Keywords: | |
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