Electrochemical oxidation of californium in carbonae solutions |
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| Authors: | Frenkel V Ya Kulyako Yu M Chistyakov V M Lebedev I A Myasoedov B F Timofeev G A Erin E A |
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| Institution: | (1) V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Academy of Sciences of the USSR, Moscow, USSR |
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| Abstract: | The electrolysis of trivalent californium, terbium and praseodimium in 2M K2CO3 solutions at pH 13.2 results in a partial oxidation of the trivalent ions to a higher oxidation state. Absorption spectra of Cf/III/ in 1M HCLO4 and in 2M K2O3 and that of oxidized californium in carbonate solution have been recorded. Incomplete oxidation is accounted to a reducing species generated at high anode potentials. |
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