| 新型一维双席夫碱铜(Ⅰ)配合物的合成、结构及荧光性质(英) |
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| 引用本文： | 黄玉婷,欧阳兴梅,岡村高明,李一志,孙为银,上山寭一.新型一维双席夫碱铜(Ⅰ)配合物的合成、结构及荧光性质(英)[J].无机化学学报,2005,21(10):1479-1482. |
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| 作者姓名： | 黄玉婷 欧阳兴梅 岡村高明 李一志 孙为银 上山寭一 |
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| 作者单位： | 1. 南京大学配位化学国家重点实验室,配位化学研究所,南京,210093
2. 日本大阪大学理学研究科高分子学科,豊中市,560-0043,日本 |
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| 基金项目： | 国家自然科学基金资助项目(No.20231020) |
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| 摘 要： | 在室温下，Cu(PPh3)2(CH3CN)2]ClO4和双席夫碱配体1，2-双(3′-吡啶基亚甲基氨基)乙烷(L)反应得到一个新型化合物Cu(PPh3)(L)](ClO4) (1)。结构分析表明该化合物属于单斜晶系，空间群为P21 /n，晶胞参数为a=1.696 6(16)
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| 关 键 词： | 晶体结构 席夫碱配体 铜化合物 荧光性质 |
| 文章编号： | 1001-4861(2005)10-1479-04 |
| 收稿时间： | 2005-04-25 |
| 修稿时间： | 2005-09-12 |
Synthesis, Structure and Photoluminescent Property of a Novel 1D Coordination Polymer of Copper(Ⅰ) Complex with Di-Schiff Base Ligand |
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| HUANG Yu-Ting,OUYANG Xing-Mei,Okamura Taka-aki,LI Yi-Zhi,SUN Wei-Yin and Ueyama Norikazu.Synthesis, Structure and Photoluminescent Property of a Novel 1D Coordination Polymer of Copper(Ⅰ) Complex with Di-Schiff Base Ligand[J].Chinese Journal of Inorganic Chemistry,2005,21(10):1479-1482. |
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| Authors: | HUANG Yu-Ting OUYANG Xing-Mei Okamura Taka-aki LI Yi-Zhi SUN Wei-Yin and Ueyama Norikazu |
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| Institution: | State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan,State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093 and Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan |
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| Abstract: | A new coordination polymer Cu(PPh3)(L)](ClO4) (PPh3=triphenylphosphine) was obtained by reaction of a di-Schiff base ligand 1,2-bis(3'-pyridylmethyleneamino)ethane (L) with Cu(PPh3)2(CH3CN)2]ClO4. The crystal structure analysis indicates that the complex crystallizes in monoclinic system, space group of P21 / n with a=1.696 6(16)nm, b=0.9124(7) nm, c=1.957 1(18) nm,β=90.797(4)°, V=3.029 7(5) nm3, and Z=4. The structure of Cu(PPh3)(L)](ClO4) is an infinite zigzag chain in which the copper(Ⅰ) atom has distorted tetrahedral coordination geometry.Photoluminescent property of the complex was investigated. CCDC: 274179. |
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| Keywords: | crystal structure schiff base ligand copper(I) complex photoluminescent property |
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