Polyimide-derived carbon nanofiber membranes as anodes for high-performance flexible lithium ion batteries |
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Authors: | Fangyuan Zhao Xin Zhao Bo Peng Feng Gan Mengyao Yao Wenjun Tan Jie Dong Qinghua Zhang |
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Institution: | State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China |
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Abstract: | The strategy of N-doping in carbon materials could provide additional Li-ion storage sites to improve their electrochemical properties. Heteroatom-containing polymers could serve as good precursors to fabricate doped carbons due to the capability to in situ dope heteroatoms into the structures. In this work, electrospun heterocyclic polyimide (PI) nanofiber membranes containing biphenyl and pyrimidine rings were carbonized to fabricate freestanding and flexible heteroatoms-containing carbon membranes. When the polymer membranes were subjected to various calcination temperatures (from 550 °C to 950 °C) and durations (0.5-10 h), the structural evolutions strongly affect their electrochemical properties as anodes for lithium ion batteries. It demonstrated that the reversible specific capacity of obtained sample treated at 650 °C for 3 h could achieve 695 mAh/g at 0.1 A/g and retain 245 mAh/g at 1.5 A/g after 300 cycles. Furthermore, the electrospun membrane maintains a good electrochemical performance at bending state as a flexible electrode. |
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Keywords: | Heteroatom Nanofiber Polyimide Anode Lithium ion battery |
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