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凝聚相中振动能量弛豫的理论研究
引用本文:田国才,邵久书. 凝聚相中振动能量弛豫的理论研究[J]. 化学进展, 2004, 16(2): 159-168
作者姓名:田国才  邵久书
作者单位:中国科学院化学研究所分子科学中心分子反应动力学国家重点实验室,北京,100080;中国科学院化学研究所分子科学中心分子反应动力学国家重点实验室,北京,100080
基金项目:中国科学院“百人计划”项目,国家自然科学基金资助项目 (No.2 0 2 2 5 310 ,90 2 0 30 14 )
摘    要:凝聚相中的振动能量弛豫是化学、物理学和生物学中一个非常重要的动力学过程.近年来, 许多实验和理论方法业已建立并用来探索它的微观机理.本文简要介绍一些常用理论方法及其应用,并对将来的发展方向作一展望.

关 键 词:振动能量弛豫  凝聚相  量子动力学  量子效应
文章编号:1005-281X(2004)02-0159-10
收稿时间:2002-12-01
修稿时间:2002-12-01

Theoretical Study of Vibrational Energy Relaxation in Condensed Phases
Tian Guoca,Shao Jiushu. Theoretical Study of Vibrational Energy Relaxation in Condensed Phases[J]. Progress in Chemistry, 2004, 16(2): 159-168
Authors:Tian Guoca  Shao Jiushu
Affiliation:(State Key Laboratory of Molecular Reaction Dynamics, Center for Molecular Science, Institute of Chemistry, CAS, Beijing 100080, China)
Abstract:Vibrational energy relaxation in condensed phases is an important dynamical process in chemistry, physics and biology. Over recent years many efforts, both theoretical and experimental, have been made to explore the mechanism. In this review article we will focus on the basic features of some frequently used theoretical methods as well as their validity in applications, and present new perspectives on developing more accurate techniques.
Keywords:vibrational energy relaxation  condensed phases  quantum dynamics  quantum effect
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