Paramagnetic resonance of Fe3+ ion in CdWO4 monocrystal

The paramagnetic spectrum of the Fe³⁺ ion in a CdWO₄ monocrystal was measured on a frequency of 9600 kMHz at 290°K. The spin-Hamiltonian of the Fe³⁺ ion was determined and had the form of (1). The constants derived for the spin-Hamiltonian areE/D=0·144±0·002,D=23·8 kMHz.

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Fe³⁺ CdWO₄

Fe³⁺ CdWO₄ 9600 kMHz 290°K. - Fe³⁺ (1), E/D 0,144±0,002 D 23,8 kMHz.

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In conclusion, the authors thank . Bárta and V. Kment from the Society for Chemical and Metallurgical Production in Ústí n/L for producing and supplying the monocrystals and for much valuable advice.