FORMATION OF REARRANGEMENT PRODUCT IN PHOTOLYSIS OF α,α-DIMETHYLDEOXYBENZOIN UPON CYCLODEXTRIN COMPLEXATION |
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| Authors: | K Pitchumani V Ramamurthy |
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| Institution: | Department of Organic Chemistry, Indian Institute of Science, Bangalore, 560 012, India |
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| Abstract: | Abstract Solid-state irradiation of cyclodextrin complexes of α,α-dimethyldeoxybenzoin results in the formation of a significant amount of rearrangement product, 4-isopropylbenzophenone, in addition to cage products. This behavior is not observed in the photolysis in solution or in micellar media. |
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