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Synthesis and structure of homochiral polymeric praseodymium tartrate |
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| Authors: | M S Zavakhina M P Yutkin D G Samsonenko D N Dybtsev V P Fedin |
| Institution: | 1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation 2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation 3. Division of the Advanced Materials Science, Pohang University of Science and Technology (POSTECH), San 31, Hyojadong, Pohang, 790-784, Republic of Korea |
| Abstract: | The homochiral metal-organic coordination polymer of the composition {Pr(H2O)2}2-(d-tart)3]·H2O was synthesized by heating an aqueous solution of praseodymium(III) chloride and d-tartaric acid (d-H2tart) in the presence of KOH. The crystal structure of the polymer was determined by X-ray crystallography and confirmed by IR spectroscopy, thermogravimetry, and elemental analysis. |
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