Perhydroisoindoliniums et perhydroisoquinoliniums: Préparation et étude stéréochimique |
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| Authors: | Joëlle Mayrargue Michel Duchon D'Engenires Marcel Miocque |
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| Institution: | Joëlle Mayrargue,Michel Duchon D'Engenières,Marcel Miocque |
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| Abstract: | By cyclization in aqueous media, 2-aminomethyl 1-alcynyl 1-cyclohexanols lead to perhydroisoindolinium or perhydroisoquinolinium salts. The stereochemistry of isolated diastereoisomers is elucidated. A stereoselectivity favouring trans junction of the rings is pointed out. |
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