Unprecedented direct oxygen atom transfer from hypervalent oxido-lambda(3)-iodanes to alpha,beta-unsaturated carbonyl compounds: synthesis of alpha,beta-epoxy carbonyl compounds |
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| Authors: | Ochiai M Nakanishi A Suefuji T |
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| Affiliation: | Faculty of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan. mochiai@ph2.tokushima-u.ac.jp |
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| Abstract: | Tetra-n-butylammonium oxido-lambda(3)-iodane, prepared from 1-hydroxy-1,2-benziodoxol-3(1H)-one by reaction with tetra-n-butylammonium fluoride, directly undergoes oxygen atom transfer to alpha,beta-unsaturated carbonyl compounds, yielding epoxides. |
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