Multiple-quantum NMR in anisotropic phases: Projections of two-dimensional MQNMR spectra |
| |
Authors: | Gary Drobny |
| |
Institution: | Department of Chemistry, University of Washington, Seattle, Washington 98195, USA |
| |
Abstract: | The use of two-dimensional transform techniques in the observation of multiple-quantum transitions in large spin systems in anisotropic environments is described. In the case of partial resolution in the ω2 dimension, it is shown that the signal to noise of the projection onto ω1 of the absolute magnitude two-dimensional multiple-quantum spectrum is considerably greater than that of the Fourier transform of the t2 = 0 cross section. In practical terms, multiple- quantum transitions of very high order may be observed with good signal to noise after acquisition periods much shorter than previously reported by cross section methods. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|