The resonance Raman spectrum of the aniline radical cation |
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| Authors: | G.N.R. Tripathi Robert H. Schuler |
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| Affiliation: | Radiation Laboratory and Department of Chemistry, University of Notre Dame, Notre Dame, Indiania 46556, USA |
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| Abstract: | The time-resolved resonance Raman spectrum of the aniline radical cation has been observed using pulse radiolysis methods. This radical exhibits a large inverse secondary isotope effect on deuteration of the NH2 group on the CN stretching frequency. Various spectral features indicate that this radical is structurally similar to the phenoxyl radical. |
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