Search for the kramers theory turnover: photochemical isomerization at very low viscosities |
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| Authors: | Scott H. Courtney Graham R. Fleming |
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| Affiliation: | Department of Chemistry and James Franck Institute, The Universtiy of Chicago, 5735 S. Ellis Avenzue, Chicago, Illinois 60637, USA |
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| Abstract: | ![]()
The rate of photochemical isomerization of diphenyl butadiene has been studied as a function of viscosity and temperature in liquid ethane and propane. The lowest viscosity studied is about one order of magnitude lower than our previous study. No evidence for a turnover or decrease in rate with decreasing viscosity was found. |
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