Beta-diiminate platinum complexes for alkane dehydrogenation |
| |
| Authors: | Fekl Ulrich Kaminsky Werner Goldberg Karen I |
| |
| Institution: | Department of Chemistry, Box 351700, University of Washington, Seattle, WA 98195-1700, USA. |
| |
| Abstract: | New five-coordinate Pt(IV) complexes {(o-R2-p-R'-C6H2)NC(R' ')}2CH]PtMe3 (R, R', R' ' = alkyl or H) are reported. The complex with R = Me, R' = tBu, R' ' = Me generates unsaturated Pt(II) species capable of alkane C-H bond activation and stoichiometric dehydrogenation. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
