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Sequential extraction partitioning of metals,sulfur, and phosphorus in bottom ash from a coal-fired power plant
Authors:Olli Dahl  Hannu Nurmesniemi
Affiliation:1. Department of Forest Product Technology, Laboratory of Chemical Pulping and Environmental Technology , Helsinki University of Technology , PO Box 6300, FI-02015, TKK, Finland;2. Stora Enso Oyj , Veitsiluoto Mill, FI-94800, Kemi, Finland
Abstract:Abstract

The herbicide trifluralin was analysed by adsorptive stripping voltammetry on a glassy carbon electrode. The linear concentration range was 2.5 × 10?7 M – 1.25 × 10?6M when using 5-min preconcentration at open circuit conditions in Britton-Robinson buffer of pH 7.0. The detection limit of trifluralin was 2.5 × 10?8M. The relative standard deviation was 3.3% at a concentration of 1.0 × 10?6M (n=5). The method was applied to the determination of trifluralin in soil with good recovery.
Keywords:Ash  Bioavailability  Coal  Extraction  Leaching
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