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Thermogravimetric investigation ofwastes from electrical and electronic equipment (WEEE)
Authors:E Kowalska  J Radomska  P Konarski  R Diduszko  J Oszczudłowski  T Opalińska  M Więch  Z Duszyc
Institution:(1) Industrial Institute of Electronics, Warsaw, Poland, 00-241, Długa 44/50 Street;(2) Institute of ElectronicMaterials Technology, Warsaw, Poland, 01-919, Wólczyńska 133 Sreet;(3) Institute of Chemistry, Świętokrzyska Academy, Kielce, Poland, 25-020, Chęcińska 5 Street;(4) Institute of Mechanized Construction and Rock Mining, Center ofWastes Management, Katowice, Poland, 40-844, Kossutha 6 Street
Abstract:Two components of electronic wastes (sample A – a mixture of three types of printed circuit boards, sample B – a mixture of electronic junctions with metal wires) were investigated using thermogravimetric analysis (TG). Thermogravimetric and derivative thermogravimetric data (TG and DTG) give information on the thermal stability of A and B samples and allows finding the correct conditions for their degradation using pyrolysis in an experimental system, built on the laboratory scale for utilization of hazardous wastes. X-ray fluorescence measurements prove that brominated flame retardant is present in sample A, whilst chlorinated flame retardant is a probable component of sample B. Preliminary liquid chromatography of oil products obtained as a result of thermal waste degradation shows that the hydrocarbons released during pyrolysis could be used as a fuel.
Keywords:electronic waste  printed circuit boards  pyrolysis  thermal treatment
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