Hydrothermal Synthesis,Crystal Structure and Characterization of a New Keggin Polyoxometalate {[Ag~I(4,4’-bipy)]_3[PW_(12)O_(40)]}·(4,4’-bipy) |
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作者姓名: | YU You-Yi CHEN Jian-Xin KE Zhi-Cong HU Li-Shan YU Ying-Hua LIN Xin-Rong ZHANG Zhi-Chun |
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作者单位: | YU You-Yi,KE Zhi-Cong,HU Li-Shan,YU Ying-Hua,LIN Xin-Rong,ZHANG Zhi-Chun(College of Chemistry and Materials Science,Fujian Normal University, Fuzhou, Fujian 350007, China);CHEN Jian-Xin(College of Chemistry and Materials Science,Fujian Normal University, Fuzhou, Fujian 350007, China; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China) |
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基金项目: | Supported by the Ministry of Education of China,the Education Department of Fujian Province,the Natural Science Foundation of Fujian Province,the State Key Laboratory of Structural Chemistry |
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摘 要: | A novel polyoxometalate {AgI(4,4'-bipy)]3PW12O40]}·(4,4'-bipy)·4H2O 1 has been synthesized hydrothermally and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The crystal of 1 belongs to the triclinic system, space group P1 with a = 11.3710(17), b = 12.0701(16), c = 13.1061(12) , α = 112.838(3), β = 94.545(6), γ = 99.526(4)°, V = 1614.4(4) 3, Mr = 3825.40, Z = 1, Dc = 3.935, μ = 22.289mm-1, F(000) = 1692, the final R = 0.0507 and wR = 0.1054. X-ray diffraction analysis reveals that the molecular structure of 1 consists of three coordinated cations AgI(4,4'-bipy)]+, a polyanion unit PW12O40]3-, and a discrete 4,4′-bipy molecule. Significantly, there exist two crystallographically independent silver(I) centers in 1 and all AgI(4,4'-bipy)]+ cations are linked with each other to form a one-dimensional Ag-4,4'-bipy polymer chain. The neighboring polymer chains are further interconnected to form a 3D framework by the covalent effect of silver atoms and terminal oxygen atoms of the polyanion. The electrochemical behaviors of 1 have also been studied in detail by cyclic voltammograms.
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关 键 词: | 多金属氧酸盐 晶体结构 联吡啶 碘化银 水热合成 射线衍射分析 n型 表征 |
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