| Syntheses and Crystal Structures of Two Octamolybdate Compounds Modified by CuⅡ-Imidazole Cations |
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| 作者单位： | FAN Li-Ming,ZHANG Xiu-Tang(Advanced Material Institute of Research, Department of Chemistry and Chemical Engineering, Qilu Normal University, Jinan 250013, China;College of Chemistry and Chemical Engineering,Liaocheng University, Liaocheng 252059, China);LI Da-Cheng,DOU Jian-Min(College of Chemistry and Chemical Engineering,Liaocheng University, Liaocheng 252059, China);WEI Pei-Hai(Advanced Material Institute of Research, Department of Chemistry and Chemical Engineering, Qilu Normal University, Jinan 250013, China) |
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| 基金项目： | supported by Financial support from the Natural Science Foundation of Shandong Province （BR2010BQ023）; Shandong Provincial Education Department and Qilu Normal University |
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| 摘 要： | Two new polyoxomolybdate compounds,namely(CuIIL2)2[CuⅡ(HL)2]2[Mo8O26(HL)2].(H2O)4(1) and [CuⅡ(HL)2]2[β-Mo8O26](HL)2(2)(HL=imidazole),were designed and synthesized under hydrothermal conditions.X-ray diffraction analyses reveal that compound 1 consists of one Mo8O26(HL)24-cluster,two CuL2,two Cu(HL)22+,and four disassociated water molecules;and compound 2 is constructed by one β-Mo8O264-cluster,two Cu(HL)22+,and two uncoordinated imidazole molecules.
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| 关 键 词： | 化合物 晶体结构 咪唑 合成 阳离子 X射线衍射分析 铜 改性 |
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