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| 钴配合物的合成晶体结构及活性研究 | |
| 引用本文： | 朱莉,廖展如,王哲明,严纯华.钴配合物的合成晶体结构及活性研究[J].无机化学学报,2002,18(7):731-734. |
| 作者姓名： | 朱莉 廖展如 王哲明 严纯华 |
| 作者单位： | 1. 湘潭师范学院,湘潭,412100 2. 华中师范大学,武汉,430070 3. 北京大学化学学院,北京,100871 |
| 基金项目： | 国家自然科学基金资助项目(No.29771012) |
| 摘 要： | The complex Co2Cl2(EGTB)]·(ClO4)2·5H2O was synthesized in methanol-aqueous solution and its crystal structure was determined by X-ray diffraction method. The crystal belongs to monoclinic with space group of P21/c. The cell parameters are a=1.42231(2)nm,b=2.53181(3)nm,c=1.43392(2)nm,β=102.0518(5)°, Z=4, F(000)=2360,Dc=1.508g·cm-3, The final R=0.0788,wR2=0.232, The catalytic rate constant of the dismutation of superoxide radicals has been obtained by means of photo reduction of nitroblue tetrazolium(NBT),and it is 1.875×106mol-1·L·s-1. |
| 关 键 词： | 双核钴配合物 晶体结构 超氧化物歧化酶 |
| 修稿时间： | 2001年12月2日 |
Synthesis and Crystal Structure of Bicobalt (Ⅱ) Complex and Study of Activity |
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| ZHU Li,LIAO Zhan-Ru,WANG Zhe-Ming and YAN Chun-Hua.Synthesis and Crystal Structure of Bicobalt (Ⅱ) Complex and Study of Activity[J].Chinese Journal of Inorganic Chemistry,2002,18(7):731-734. | |
| Authors: | ZHU Li LIAO Zhan-Ru WANG Zhe-Ming and YAN Chun-Hua |
| Institution: | Department of Chemistry, Xiangtan Normal University, Xiantan 411100,Deparment of Cchemistry, Huazhong Normal University, Wuhan 430070,Chemistry College of Peking University, Beijing 100871 and Chemistry College of Peking University, Beijing 100871 |
| Abstract: | |
| Keywords: | binuclear cobalt?complex crystal structure superoxi de dismutase |
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