Abstract: | The influence of Van der Waals forces on the lifetime of coherently excited hyperfine-states |FimFi〉 and |FimFi〉 of alkalilike atoms i by collissions with inert gas atoms j in the groundstate |FjmFi〉 has been examined. To do this the timedependent Schrödinger equation has been solved on taking into account a static magnetic field, a radiation field and a Van der Waals force. Introducing an impact parameter model for the colliding atoms with small scattering angles which form a quasimolecule |μ〉 = |FimFiFjmFi 〉 an expression for the cross section σμμ has been derived which determines the halfwidth Γ μμ of the coherently excited states. On making use of the irreducible tensor representation the calculation of the cross-section has been reduced to the calculation of multipole transitions. The result has been applied e. g. to the coherently excited 3d104p2P3/2-states of Cu I colliding by dipole-dipole interaction with inert gas atoms He I, and Ar I in the ground state. The values agree well with data which have been derived from zero-level-crossing experiments. |