| Electrochemical Study of Trinuclear Metal Complexes ［M_3O_2（O_2CCH_3）_6（H_2O）_3］~（2＋）（M_3＝Mo_3，MoW_2，W_3） |
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| 作者姓名： | Liu Huang Xu Li Huang Jin-Shun Yan Duan-Chao Zhang Qian-Er |
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| 作者单位： | Fujian Institute of Research on the Structure of Matter，Academia Sinica;State Key Laboratory of Structural Chemistry，Fuzhou，Fujian，350002 |
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| 摘 要： | ＥｌｅｃｔｒｏｃｈｅｍｉｃａｌＳｔｕｄｙｏｆＴｒｉｎｕｃｌｅａｒＭｅｔａｌＣｏｍｐｌｅｘｅｓ［Ｍ_３Ｏ_２（Ｏ_２ＣＣＨ_３）_６（Ｈ_２Ｏ）_３］~（２＋）（Ｍ_３＝Ｍｏ_３，ＭｏＷ_２，Ｗ_３）ＬｉｕＨｕａｎｇ；ＸｕＬｉ；ＨｕａｎｇＪｉｎ－Ｓｈｕｎ；ＹａｎＤ...
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Electrochemical Study of Trinuclear Metal Complexes[M_3O_2(O_2CCH_3)_6(H_2O)_3]￣(2+)(M_3=Mo_3,MoW_2,W_3) |
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| Liu Huang,Xu Li,Huang Jin-Shun,Yan Duan-Chao,Zhang Qian-Er.Electrochemical Study of Trinuclear Metal Complexes[M_3O_2(O_2CCH_3)_6(H_2O)_3]￣(2+)(M_3=Mo_3,MoW_2,W_3)[J].Chinese Journal of Structural Chemistry,1994(2). |
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| Authors: | Liu Huang Xu Li Huang Jin-Shun Yan Duan-Chao Zhang Qian-Er |
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| Abstract: | In this paper detailed studies of the cyclic voltammetry(CV) of trinuclear metal cluster compounds M_3O_2(O_2CCH_3,)6(H,O),j z+ (M,=Mo3,MoW2,W3) are reported.The result of CV shows that they are similar to each other.There are a reversible redox peak near-0. 48 V and an irreversible reduced peak near-1.10 V in the scan range of + l.0 V to l. 5 V.It implies that the M_3O_2,clusters might gain one electron to be further reduced.But the two-electron-reduced product of M_3O_2 clusters are instable.The theoretical calculations(EHMO) agree well with the result of the CV experiment. |
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| Keywords: | cyclic voltammetry electrochemistry trinuclear metal cluster preparation |
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